Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrate

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Bis[2-(1H-imidazol-2-yl-κN 3)-1H-imidazol-3-ium]silver(I) trinitrate

The synthesis of the title salt, [Ag(C(6)H(7)N(4))(2)](NO(3))(3), was carried out employing a 1:2 molar ratio of 2,2'-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N-Ag-N = 177.01 (17)°]. The crystal structure displays N-H⋯O and C-H⋯O hydrogen-bonding inter-actions.

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3-(1H-Imidazol-1-yl)propanaminium picrate

IN THE TITLE SALT [SYSTEMATIC NAME: 3-(1H-imidazol-1-yl)propanaminium 2,4,6-tri-nitro-phenolate], C6H12N3 (+)·C6H2N3O7 (-), there are five independent cation-anion pairs (A, B, C, D, E) in the asymmetric unit. In the cation, the ammonium group is protonated with the amino-propyl group nearly at right angles to the mean plane of the imidazole ring showing C-N-C-C torsion angles ranging from 79.6...

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3-(1H-Imidazol-1-yl)propane­nitrile

The title compound, C(6)H(7)N(3), has an ethyl-ene group connecting an imidazole ring and a -CN group. These groups are in a staggered conformation. The shortest inter-molecular contact is found between the imidazole N atom and a -CH(2)- group of a neighboring mol-ecule.

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2-[(1H-Imidazol-2-yl)disulfan­yl]-1H-imidazole

In the title molecule, C(6)H(6)N(4)S(2), a twofold rotation axis passes through the mid-point of the S-S bond. The C-S-S-C torsion angle is 83.62 (17)°. π-π stacking between imidazole rings of adjacent mol-ecules is observed in the crystal structure, the centroid-centroid distance being 3.447 (2) Å. Inter-molecular N-H⋯S hydrogen bonding results in the formation of a linear chain in the c-axis ...

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2-(1H-Imidazol-1-yl)-4,6-dimethyl­pyrimidine

The asymmetric unit of the title compound, C(9)H(10)N(4), consists of two mol-ecules in which the dihedral angles between the planes of the imidazole and pyrimidine rings are 4.8 (1) and 2.1 (1)°.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811021799